Author, Institution: Kristina Vasiliauskienė, Kaunas University of Technology
Science area, field of science: Technological Sciences, Chemical Engineering, T005
Scientific Supervisor: Assoc. Prof. Dr. Anatolijus Eisinas (Kaunas University of Technology, Technological Sciences, Chemical Engineering, T005)
Dissertation Defense Board of Chemical Engineering Science Field:
Prof. Dr. Raimundas Šiaučiūnas (Kaunas University of Technology, Technological Sciences, Chemical Engineering, T005) – chairperson
Assoc. Prof. Dr. Irmantas Barauskas (Kaunas University of Technology, Technological Sciences, Chemical Engineering, T005)
Prof. Dr. Hab. Aivaras Kareiva (Vilnius University, Natural Sciences, Chemistry, N003)
Prof. Dr. Jūratė Kumpienė (Luleå University of Technology, Sweden, Technological Sciences, Materials Engineering, T008)
Prof. Dr. Eugenijus Valatka (Kaunas University of Technology, Technological Sciences, Chemical Engineering, T005)
Dissertation defense meeting will be at Rectorate Hall of Kaunas University of Technology (K. Donelaičio 73 – 402, Kaunas)
The doctoral dissertation is available at the library of Kaunas University of Technology (Gedimino 50, Kaunas)
Annotation: Recently, the synthesis, structure, and applications of calcium aluminate –mayenite have received considerable attention in the scientific literature. All methods currently used for the synthesis of mayenite can be divided into three broad groups. Two-stage production methods such as the synthesis of calcium hydroaluminate precursors of mayenite and the heat treatment of the resulting products to form the target synthesis product are the least studied. This technology has been applied to the synthesis of mayenite, but the scientific literature provides only fragmentary data. The aim of the dissertation is to determine the influence of two-stage synthesis conditions on the formation and properties of mayenite derivatives and propose rational areas of applications. Researched that increasing the combustion temperature (from 350 to 900°C) increases the specific surface area and pore volume of the mayenite derivatives almost threefold. The additive of mayenite derivatives, irrespective of the temperature at which it is obtained, modifies the hydration process of Portland cement: promotes calcium sulphate dihydrate reacting, the formation of ettringite, and increases the total amount of heat released. The adsorption of Cu2+ and SO42- ions is a major focus of this work, it was determined that the total adsorption capacity of synthetic mayenite derivatives for Cu2+ and SO42- ions increases with increasing combustion temperature of the mayenite derivatives and the initial concentration of copper sulphate solution. For the first time, it has been shown that, after thermal activation, mayenite derivatives can be used for the re-adsorption of Cu2+ and SO42- ions from aqueous solutions. It has been investigated that the products obtained after two cycles of adsorption and additional heat treatment can be used as accelerators for the hydration process of Portland cement.
May 10 d. 10:00
Rectorate Hall at Kaunas University of Technology (K. Donelaičio 73-402, Kaunas)
Įtraukti į iCal
